https://ogma.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 Formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) from oxidation of 4,4'-dichlorobiphenyl (4,4'-DCB) https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:42740  600°C) lead to selective formation of a small number of lower-chlorinated pollutants, whereas reactive surfaces, as evident from literature, engender catalytic (but non-selective) appearance of a large number of higher-chlorinated and toxic chloroaryl congeners, even at temperature of less than 300°C. Results from the density functional theory (DFT) calculations indicate that, majority of the detected congeners of PCDF arise from the oxidative transformation of the parent 4,4′-DCB; i.e., not from the commonly suggested precursors of chlorinated phenols and benzenes. Our findings have significant importance to understanding the emission of PCB and PCDD/F in combustion processes.]]> Wed 24 May 2023 15:48:24 AEST ]]> PCDD/F formation in flaming combustion, smoldering, and oxidative pyrolysis of 'eco-friendly' treated wood https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:540 Thu 25 Jul 2013 09:10:25 AEST ]]> Conversion of wood pyrolysates to PCDD/F https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:8034 Sat 24 Mar 2018 08:36:48 AEDT ]]> Oxidation reactions and spontaneous ignition of linseed oil https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:12434 Sat 24 Mar 2018 08:15:28 AEDT ]]> Formation of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) in oxidation of captan pesticide https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:12273 Sat 24 Mar 2018 08:10:12 AEDT ]]> Dynamic behaviour of coal macerals during pyrolysis - associations between physical, thermal and chemical changes https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:18925 Sat 24 Mar 2018 07:59:00 AEDT ]]> Experimental study of influence of temperature on fuel-N conversion and recycle NO reduction in oxyfuel combustion https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:17777 Sat 24 Mar 2018 07:57:41 AEDT ]]> Formation of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/F) by precursor pathways in oxidation of pesticide alpha-cypermethrin https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:20190 Sat 24 Mar 2018 07:51:32 AEDT ]]> Theoretical investigation into the low-temperature oxidation of ethylbenzene https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:20191 Sat 24 Mar 2018 07:51:32 AEDT ]]> Gas phase pyrolysis of endosulfan and formation of dioxin precursors of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:32361 Mon 28 May 2018 11:46:59 AEST ]]> Mechanisms of thermal decomposition of cyclodiene pesticides, identification and possible mitigation of their toxic products https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:37366 Mon 19 Oct 2020 11:19:27 AEDT ]]>